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Safety Data Sheet EN

Diisopropylamine

CAS 108-18-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Diisopropylamine
Product Code
471224
Chemical Name
Diisopropylamine

Regulatory Identifiers

CAS Number
108-18-9 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

M

Merck Life Science BV/SRL

distributor

Brusselsesteenweg 288, B-3090 OVERIJSE

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 3 H331
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

Hazard Statements

H225 Highly flammable liquid and vapor.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
diisopropylamine EC: 203-558-5 108-18-9 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2), Foam, Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides, Nitrogen oxides (NOx), Flash back possible over considerable distance., Container explosion may occur under fire conditions., Combustible., Pay attention to flashback., Vapors are heavier than air and may spread along floors., Development of hazardous combustion gases or vapours possible in the event of fire., Forms explosive mixtures with air at ambient temperatures.

Instructions

Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains. Risk of explosion.

Cleanup methods

Take up carefully with liquid-absorbent material (e.g. Chemizorb®).

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: Nitrile rubber, Minimum layer thickness: 0,4 mm, Break through time: 480 min, Material tested: Camatril® (KCL 730 / Aldrich Z677442, Size M). Splash contact: Material: butyl-rubber, Minimum layer thickness: 0,7 mm, Break through time: 30 min, Material tested: Butoject® (KCL 898). When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Tightly fitting safety goggles. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Required when vapours/aerosols are generated. Recommended Filter type: Filter type ABEK. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Colour
colorless
Metal Corrosion
---
Solubility
---
Relative Evaporation Rate
---
Melting Point
-61 °C
Crystallisation Point
---
Lower Explosive Limit
1,1 %(V)
Upper Explosive Limit
7,1 %(V)
Density
0,722 g/mL at 25 °C
Odor Threshold
---
State Under Standard Conditions
---
Solidification Point
---
Odor
amine-like
Vapor Pressure
93,33 hPa at 20 °C
Evaporation Rate
---
Kinematic Viscosity
No data available
Auto Ignition Temperature
295 °C at 1.007 hPa
Physical State
liquid
Decomposition Temperature
---
Cloud Point
---
Properties Status
---
Relative Density
---
Boiling Point
84 °C
Solubility In Water
miscible
Ph
11,8 at 6 g/l at 20 °C
Partition Coefficient
log Pow: 0,4 at 20 °C
Freezing Point
---
Solubility In Fat
---
Dynamic Viscosity
0,4 mPa.s at 25 °C
Flammability
---
Softening Point
---
Voc Content
---
Molecular Weight
---
Bulk Density
---
Form
---
Appearance
---
Explosive Limits
---
Physical State Data
liquid
Colour Intensity
---
Flash Point
-13,45 °C
Vapor Density
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

Vapors may form explosive mixture with air.

Hazardous reactions

Risk of ignition or formation of inflammable gases or vapours with: Strong oxidizing agents, nitrates, perchlorates, Aluminum, Peroxides. Exothermic reaction with: halogens, acids. Caution! In contact with nitrites, nitrates, nitrous acid possible liberation of nitrosamines!

Avoid

Warming.

Incompatible

Aluminum

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1158
Shipping Name
DIISOPROPYLAMINE
Transport Class
3 (8)
Packing Group
II
ADR

Tunnel restriction code : (D/E)

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Diisopropylamine?

The signal word is danger.

What is the physical form of Diisopropylamine?

Diisopropylamine is a liquid with colorless color. It has amine-like odor.

What is Diisopropylamine used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Diisopropylamine?

This substance has 6 hazard statements:

  • H225: Highly flammable liquid and vapor.
  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H331: Toxic if inhaled.
  • H335: May cause respiratory irritation.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of Diisopropylamine?

The melting point is -61 °C and the boiling point is 84 °C.