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Safety Data Sheet EN

Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis

CAS 79-10-7

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis
Product Code
8.00181
Chemical Name
Acrylic acid

Regulatory Identifiers

CAS Number
79-10-7 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration or the annual tonnage does not require a registration.

Identified Uses

Chemical for synthesis

Manufacturers & Suppliers

S

Sigma-Aldrich Ireland Limited

national supplier

Vale Road, Arklow, CO WICKLOW, CO WICKLOW, IRELAND

+353 402-20300

Emergency Contacts

CHEMTREC

+(353)-19014670

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H332
Acute Tox. Cat. 4 H312
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H226 Flammable liquid and vapor.
H302 + H312 + H332
H312
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Formula : C3H4O2 Molecular weight : 72.06 g/mol CAS-No. : 79-10-7 EC-No. : 201-177-9 Index-No. : 607-061-00-8

Chemical Name CAS Number Concentration Hazardous
acrylic acid EC: 201-177-9 79-10-7 --- Yes

Millipore- 8.00181 The life science business of Merck operates as MilliporeSigma in the US and Canada MERCK For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Immediate Medical Attention

Immediately call in physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water, Foam, Carbon dioxide (CO2), Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides, Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Remove container from danger zone and cool with water.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains. Risk of explosion.

Cleanup methods

Take up with liquid-absorbent material (e.g. Chemizorb®). Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Adhere to recommended storage temperature. Crystallises at approx. +13°C. Do not store below +15°C. Risk of explosion. Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: butyl-rubber, Minimum layer thickness: 0.7 mm, Break through time: 480 min, Material tested: Butoject® (KCL 898). Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0.4 mm, Break through time: 120 min, Material tested: Camatril® (KCL 730 / Aldrich Z677442, Size M). Recommendation applies to conditions stated in EN 16523-1.

Eyes

Tightly fitting safety goggles. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Metal Corrosion
---
Partition Coefficient
log Pow: 0.46 at 25 °C - Bioaccumulation is not expected.
Flammability
No data available
Appearance
---
Explosive Limits
---
Evaporation Rate
---
Form
---
Solidification Point
---
Kinematic Viscosity
No data available
Ph
No data available
Relative Evaporation Rate
---
Odor Threshold
---
Decomposition Temperature
No data available
Freezing Point
---
Flash Point
48.5 °C - closed cup - DIN 51755 Part 1
Auto Ignition Temperature
438 °C at 1,013 hPa
Boiling Point
141 °C at 1,013 hPa
Vapor Pressure
5.29 hPa at 25 °C
Properties Status
---
Physical State Data
liquid
Relative Density
1.05 at 20 °C
Cloud Point
---
Solubility
---
Vapor Density
---
State Under Standard Conditions
---
Solubility In Water
1,000 g/l at 25 °C
Softening Point
---
Bulk Density
---
Colour Intensity
---
Odor
No data available
Solubility In Fat
---
Molecular Weight
---
Density
1.05 g/cm³ at 20 °C
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Physical State
liquid
Colour
colorless
Voc Content
---
Melting Point
13 °C
Crystallisation Point
---
Dynamic Viscosity
1.15 mPa.s at 25 °C
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature). Prolonged storage of the product can cause the stabilizer to lose its effectiveness. Contains the following stabilizer(s): hydroquinone monomethyl ether (0.02 %)

Reactivity

Vapor/air-mixtures are explosive at intense warming.

Hazardous reactions

Risk of explosion with: Oxidizing agents, polymerisation initiators, Peroxides, Oxygen. Violent polymerization may be caused by: alkali hydroxides, Amines, Ammonia, sulfuric acid, mercaptans, azides, Ether, Ketones, Aldehydes, nitrates, nitrites. Increased reactivity with: anhydrides

Avoid

Avoid temperatures below recommended storage temperature. Heating.

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Waste material must be disposed of in accordance with the national and local regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2218
Shipping Name
ACRYLIC ACID, STABILIZED
Transport Class
8 (3)
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis?

The signal word is danger.

What is the physical form of Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis?

Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis is a liquid with colorless color. It has no data available odor.

What is Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis used for?

Chemical for synthesis

What are the hazard statements for Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis?

This substance has 6 hazard statements:

  • H226: Flammable liquid and vapor.
  • H302 + H312 + H332:
  • H312:
  • H314: Causes severe skin burns and eye damage.
  • H335: May cause respiratory irritation.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis?

The melting point is 13 °C and the boiling point is 141 °C at 1,013 hPa.