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Safety Data Sheet EN

Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis

CAS 79-10-7
EC 607-061-00-8

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis
Product Code
8.00181
Chemical Name
Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis

Regulatory Identifiers

CAS Number
79-10-7 Check regulations →
EC Number
607-061-00-8 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration or the annual tonnage does not require a registration.

Identified Uses

Chemical for synthesis

Manufacturers & Suppliers

S

Sigma-Aldrich Ireland Limited

national supplier

Vale Road Arklow CO WICKLOW CO WICKLOW IRELAND

+353 402-20300

Emergency Contacts

CHEMTREC

+(353)-19014670

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H332
Acute Tox. Cat. 4 H312
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H226 Flammable liquid and vapor.
H302 + H312 + H332
H312
H314 Causes severe skin burns and eye damage.
H335
H335 May cause respiratory irritation.
H410
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
acrylic acid EC: 201-177-9 79-10-7 --- Yes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately.

Immediate Medical Attention

No data available

Medical Treatment

No data available

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water Foam Carbon dioxide (CO2) Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides. Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Remove container from danger zone and cool with water.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains. Risk of explosion.

Cleanup methods

Take up with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Adhere to recommended storage temperature. Crystallises at approx. +13°C. Do not store below +15°C. Risk of explosion. Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Recommended storage temperature see product label.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: butyl-rubber, Minimum layer thickness: 0.7 mm, Break through time: 480 min, Material tested: Butoject® (KCL 898). This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0.4 mm, Break through time: 120 min, Material tested: Camatril® (KCL 730 / Aldrich Z677442, Size M). This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Evaporation Rate
---
Partition Coefficient
0.46
Molecular Weight
---
Physical State Data
liquid
Appearance
---
Metal Corrosion
---
Cloud Point
---
Odor
No data available
Bulk Density
---
Boiling Point
141 °C
Decomposition Temperature
No data available
Vapor Density
---
Relative Evaporation Rate
---
Properties Status
---
Melting Point
13 °C
Voc Content
---
Dynamic Viscosity
1.15 mPa.s
Physical State
liquid
Density
1.05 g/cm³
Crystallisation Point
---
Auto Ignition Temperature
438 °C
Flammability
No data available
Upper Explosive Limit
No data available
Softening Point
---
Freezing Point
---
Kinematic Viscosity
No data available
Colour
colorless
Solubility In Water
1,000 g/l
Colour Intensity
---
Solidification Point
---
Vapor Pressure
5.29 hPa
Lower Explosive Limit
No data available
Solubility In Fat
---
Flash Point
48.5 °C
Explosive Limits
---
State Under Standard Conditions
---
Odor Threshold
---
Relative Density
1.05
Ph
No data available
Form
---
Solubility
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Prolonged storage of the product can cause the stabilizer to lose its effectiveness. The product is chemically stable under standard ambient conditions (room temperature). Contains the following stabilizer(s): - hydroquinone monomethyl ether (0.02 %)

Reactivity

Vapor/air-mixtures are explosive at intense warming.

Hazardous reactions

Risk of explosion with: - Oxidizing agents - polymerisation initiators - Peroxides - Oxygen Violent polymerization may be caused by: - alkali hydroxides - Amines - Ammonia - sulfuric acid - mercaptans - azides - Ether - Ketones - Aldehydes - nitrates - nitrites increased reactivity with: - anhydrides

Avoid

Avoid temperatures below recommended storage temperature. Heating.

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2218
Shipping Name
ACRYLIC ACID, STABILIZED
Transport Class
8 (3)
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis?

The signal word is danger.

What is the physical form of Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis?

Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis is a liquid with colorless color. It has no data available odor.

What is Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis used for?

Chemical for synthesis

What are the hazard statements for Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis?

This substance has 8 hazard statements:

  • H226: Flammable liquid and vapor.
  • H302 + H312 + H332:
  • H312:
  • H314: Causes severe skin burns and eye damage.
  • H335:
  • H335: May cause respiratory irritation.
  • H410:
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of Acrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis?

The melting point is 13 °C and the boiling point is 141 °C.

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