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Safety Data Sheet EN

Peroxyacetic acid, ca. 35 wt.% solution in diluted acetic acid, stabilized

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Peroxyacetic acid, ca. 35 wt.% solution in diluted acetic acid, stabilized
Product Code
257750000; 257750250; 257751000; 257755000
Chemical Name
Peroxyacetic acid
Synonyms
Peracetic acid

Regulatory Identifiers

CAS Number
N/A
UFI Code
U566-D3VQ-3XOD-AAFP

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

F

Fisher Scientific UK

distributor

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

A

Acros Organics BVBA

manufacturer

Janssen Pharmaceuticalaan 3a 2440 Geel, Belgium

Emergency Contacts

US Information

001-800-ACROS-01

Europe Information

+32 14 57 52 11

Emergency Number US

001-201-796-7100

Emergency Number Europe

+32 14 57 52 99

CHEMTREC US

001-800-424-9300

CHEMTREC Europe

001-703-527-3887

National Poisons Information Centre (NPIC)

01 809 2166

8am-10pm, 7 days a week

Malta

+356 2395 2000

Cyprus

+357 2240 5611

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Org. Perox. Cat. D H242
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H332
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335
Aquatic Acute Cat. 1 H400

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H227 Combustible liquid
H242 Heating may cause a fire
H301 + H331 Toxic if swallowed or if inhaled
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
H335 May cause respiratory irritation
H410 Very toxic to aquatic life with long lasting effects

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Acetic acid EC: 200-580-7 64-19-7 46 - 55% Yes
Peroxyacetic acid EC: 201-186-8 79-21-0 34 - 39% Yes
Hydrogen peroxide EC: 231-765-0 7722-84-1 11 - 15% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If not breathing, give artificial respiration. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Remove to fresh air. Immediate medical attention is required.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Ingestion

Do NOT induce vomiting. Call a physician or poison control center immediately.

Symptoms: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water mist may be used to cool closed containers. CO2, dry chemical, dry sand, alcohol-resistant foam.

Unsuitable media

No information available.

Specific hazards

Thermal decomposition can lead to release of irritating gases and vapors. The product causes burns of eyes, skin and mucous membranes. Oxidizer: Contact with combustible/organic material may cause fire. May ignite combustibles (wood paper, oil, clothing, etc.). Combustible material. Containers may explode when heated.

Firefighter Protection

Wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.

Environmental

Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains.

Cleanup methods

Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal.

Materials: inert absorbent material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Do not breathe mist/vapors/spray. Do not ingest. If swallowed then seek immediate medical assistance. Keep away from clothing and other combustible materials. Keep away from open flames, hot surfaces and sources of ignition.

Storage

Keep refrigerated. Keep containers tightly closed in a dry, cool and well-ventilated place.

Hygiene

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.

Fire prevention

Keep away from clothing and other combustible materials. Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Use explosion-proof electrical/ventilating/lighting/equipment. Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Butyl rubber; Breakthrough time: See manufacturers recommendations; Glove thickness: -; EU standard: EN 374; Glove comments: (minimum requirement)

Eyes

Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced Recommended Filter type: Particulates filter conforming to EN 143 Acid gases filter Type E Yellow conforming to EN14387. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask :- Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141 When RPE is used a face piece Fit Test should be conducted

Skin/Body

Long sleeved clothing

Environmental

Prevent product from entering drains. Do not allow material to contaminate ground water system. Local authorities should be advised if significant spillages cannot be contained.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear Colorless
Colour
---
Colour Intensity
---
Form
---
Odor
Strong pungent
Odor Threshold
No data available
Ph
-1.2
Melting Point
-44 °C / -47.2 ºF
Boiling Point
105 ℃ / 221 °F
Flash Point
62 °C / 143.6 °F, Method - No information available
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
20 hPa @ 20 ℃
Vapor Density
---
Relative Density
---
Bulk Density
Not applicable
Density
1.130
Flammability
Combustible liquid
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
Acetic acid: -0.2, Hydrogen peroxide: -1.1
Solubility In Water
Soluble
Solubility In Fat
---
Molecular Weight
76.05
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions

Reactivity

Yes

Hazardous reactions

None under normal processing.

Avoid

Heat, flames and sparks. Keep away from open flames, hot surfaces and sources of ignition. Incompatible products. Combustible material. Excess heat.

Incompatible

combustible/organic material

Decomposition

Carbon monoxide (CO). Carbon dioxide (CO2). Sulfur oxides.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity Ecotoxicity effects

The product contains following substances which are hazardous for the environment. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

The product contains substances hazardous to the environment, specifically toxic to aquatic organisms with potential long-term adverse effects.

12.1. Toxicity Ecotoxicity effects

Component: Acetic acid. Freshwater Fish: Pimephales promelas: LC50 = 88 mg/L/96h Lepomis macrochirus: LC50 = 75 mg/L/96h. Water Flea: EC50 = 95 mg/L/24h. Freshwater Algae: -

12.1. Toxicity Ecotoxicity effects

Component Freshwater Fish Water Flea Freshwater Algae

12.1. Toxicity Ecotoxicity effects

Component Freshwater Fish Water Flea Freshwater Algae Hydrogen peroxide LC50: 16.4 mg/L/96h (P.promelas) EC50 7.7 mg/L/24h EC50 2.5 mg/L/72h

12.1. Toxicity Ecotoxicity effects

Photobacterium phosphoreum: EC50 = 8.8 mg/L/15 min Photobacterium phosphoreum: EC50 = 8.8 mg/L/25 min Photobacterium phosphoreum: EC50 = 8.8 mg/L/5 min

12.1. Toxicity Ecotoxicity effects

Ecotoxicity effects Component: Peroxyacetic acid Microtox: M-Factor: 1 (acute) 10 (Chronic)

12.2. Persistence and degradability

Persistence Degradation in sewage treatment plant Readily biodegradable Soluble in water, Persistence is unlikely, based on information available. Contains substances known to be hazardous to the environment or not degradable in waste water treatment plants.

Readily biodegradable. Persistence is unlikely. Contains substances known to be hazardous to the environment or not degradable in waste water treatment plants.

12.3. Bioaccumulative potential

Bioaccumulation is unlikely
Component Freshwater Fish Water Flea Freshwater Algae
Peroxyacetic acid LC50: = 1.1 mg/L, 96h semi-static (Lepomis macrochirus)

Bioaccumulation is unlikely.

12.3. Bioaccumulative potential

Component log Pow Bioconcentration factor (BCF) Acetic acid -0.2 No data available

12.3. Bioaccumulative potential

Component log Pow Bioconcentration factor (BCF)

12.4. Mobility in soil

The product is water soluble, and may spread in water systems . Will likely be mobile in the environment due to its water solubility. Highly mobile in soils

The product is water soluble and highly mobile in soils.

12.5. Results of PBT and vPvB assessment

No data available for assessment.

12.6. Endocrine disrupting properties

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors

12.7. Other adverse effects

Persistent Organic Pollutant Ozone Depletion Potential This product does not contain any known or suspected substance This product does not contain any known or suspected substance
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3105
Shipping Name
ORGANIC PEROXIDE TYPE D, LIQUID
Transport Class
5.2
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Peroxyacetic acid, ca. 35 wt.% solution in diluted acetic acid, stabilized known by?

Peroxyacetic acid, ca. 35 wt.% solution in diluted acetic acid, stabilized is also known as: Peracetic acid

What is the hazard signal word for Peroxyacetic acid, ca. 35 wt.% solution in diluted acetic acid, stabilized?

The signal word is danger.

What is the physical form of Peroxyacetic acid, ca. 35 wt.% solution in diluted acetic acid, stabilized?

Peroxyacetic acid, ca. 35 wt.% solution in diluted acetic acid, stabilized is a liquid appearing as clear colorless . It has strong pungent odor.

What is Peroxyacetic acid, ca. 35 wt.% solution in diluted acetic acid, stabilized used for?

Laboratory chemicals.

What are the hazard statements for Peroxyacetic acid, ca. 35 wt.% solution in diluted acetic acid, stabilized?

This substance has 7 hazard statements:

  • H227: Combustible liquid
  • H242: Heating may cause a fire
  • H301 + H331: Toxic if swallowed or if inhaled
  • H312: Harmful in contact with skin
  • H314: Causes severe skin burns and eye damage
  • H335: May cause respiratory irritation
  • H410: Very toxic to aquatic life with long lasting effects

What is the melting point of Peroxyacetic acid, ca. 35 wt.% solution in diluted acetic acid, stabilized?

The melting point is -44 °C / -47.2 ºF and the boiling point is 105 ℃ / 221 °F.

Component log Pow Bioconcentration factor (BCF)
Hydrogen peroxide -1.1 No data available