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Safety Data Sheet EN

TAR 4X P / 5X P

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
TAR 4X P / 5X P
Synonyms
Tar 4X P, Tar 5X P

Regulatory Identifiers

CAS Number
N/A
UFI Code
R910-G0N1-J007-RD9N

Identified Uses

Formulation and end use of coatings, paints, waterproofing material and sealants (adhesives).

Uses advised against

None identified. See section 15 for possible restrictions on use.

Manufacturers & Suppliers

BILBAÍNA DE ALQUITRANES S. A. logo

BILBAÍNA DE ALQUITRANES S. A.

manufacturer

C/ Obispo Olaetxea , nº 49, 48903 - LUTXANA (BARAKALDO), BIZKAIA (SPAIN)

+34 94 497 00 20

http://www.bilbaina.com

Emergency Contacts

Emergency Contact

+34 944 97 00 20

Available 24 hours

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Aquatic Chronic Cat. 3
Carc. Cat. 1B
Eye Irrit. Cat. 2
Flam. Liq. Cat. 3
Muta. Cat. 1B
Repr. Cat. 1B
STOT RE Cat. 2
Skin Irrit. Cat. 2
Skin Sens. Cat. 1A

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H340 May cause genetic defects.
H350 May cause cancer.
H360FD May damage fertility. May damage the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P308 + P313 IF exposed or concerned: Get medical advice/attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Petroleum pitch EC: 269-110-6 68187-58-6 40 - 70% Yes
Creosote oil, acenaphthene fraction, Wash Oil EC: 292-605-3 90640-84-9 10 - 25% Yes
Distillates (coal tar), heavy oils, Heavy Anthracene Oil EC: 292-607-4 90640-86-1 10 - 25% Yes
Xylene EC: 215-535-7 1330-20-7 10 - 20% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Take the victim into open air; keep them warm and calm. If breathing is irregular or stops, perform artificial respiration.

Symptoms: Fumes may irritate respiratory system or lungs.

Skin contact

Remove contaminated clothing. Wash skin vigorously with water and soap or a suitable skin cleaner. NEVER use solvents or thinners.

Symptoms: IRRITANT MIXTURE. Its repeated or prolonged contact with the skin or mucous membranes can cause irritant symptoms such as reddening of the skin, blisters, or dermatitis. Some of the symptoms may not be immediate. They can cause allergic reactions on the skin.

Eye contact

Remove contact lenses, if present and if it is easy to do. Wash eyes with plenty of clean and cool water for at least 15 minutes while pulling eyelids up, and seek medical assistance.

Symptoms: Possible irritation..

Ingestion

If accidentally ingested, seek immediate medical attention. Keep calm. NEVER induce vomiting.

Symptoms: The product can cause discomfort when swallowed.

Immediate Medical Attention

Seek medical assistance for eye contact. Seek immediate medical attention for ingestion.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Extinguisher powder or CO2. In case of more serious fires, also alcohol-resistant foam and water spray.

Unsuitable media

Do not use a direct stream of water to extinguish. In the presence of electrical voltage, you cannot use water or foam as extinguishing media.

Specific hazards

Thermal decomposition or combustion can release carbon oxides, nitrogen oxides, sulfur dioxide, hydrocarbons, and other toxic gases or vapors. In the event of a fire, the vapors and decomposition products can form flammable/explosive mixtures with air. Exposure to these products can be harmful to health.

Instructions

Use water to cool tanks, cisterns, or containers close to the heat source or fire. Take wind direction into account.

Firefighter Protection

According to the size of the fire, it may be necessary to use protective suits against the heat, individual breathing equipment, gloves, protective goggles or facemasks, and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Alert your colleagues and ensure good ventilation while evacuating the place. Keep unnecessary personnel away from the affected area. Do not touch or walk-through spilled material.

Environmental

Do not allow to enter drains, sewers or watercourses. The product should not be dumped in nature but collected and delivered according to agreement with the local authorities.

Cleanup methods

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders). Deposit waste in closed and suitable containers for disposal.

Materials: sand, diatomite, acid binders, universal binders

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with skin and eyes. Avoid aerosol formation. Avoid inhalation of vapor and mist. Smoking, eating, and drinking should be prohibited in the application area. Pregnant or lactating women should not handle this product. To reduce sensitivity to the sun, use a sunscreen with a sun protection factor (SPF50+).

Storage

Keep the container tightly closed, isolated from heat sources, sparks, and fire.

Hygiene

Smoking, eating, and drinking should be prohibited in the application area.

Fire prevention

Keep the container tightly closed, isolated from heat sources, sparks, and fire. Do not use tools that can produce sparks. The product should only be used in areas where all unprotected flames and other ignition sources have been eliminated.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide adequate ventilation, which can be achieved by using good local exhaust-ventilation and a good general exhaust system. Consult the attached exposure scenarios (see Annex I).

Hands

PPE: Protective gloves against chemicals. Characteristics: «CE» marking, category III. CEN standards: EN 374, EN 420. Maintenance: Keep in a dry place, away from any sources of heat, and avoid exposure to sunlight as much as possible. Do not make any changes to the gloves that may alter their resistance, or apply paints, solvents or adhesives. Observations: Gloves should be of the appropriate size and fit the user's hand well, not being too loose or too tight. Always use with clean, dry hands. Material: The choice of material and thickness of the glove depends on the risks of the work to be carried out and its duration. Consult your PPE supplier for more information.

Eyes

PPE: Protective goggles with built-in frame. Characteristics: «CE» marking, category II. Eye protector with built-in frame for protection against dust, smoke, fog and vapour. CEN standards: EN 166. Maintenance: Visibility through lenses should be ideal. Therefore, these parts should be cleaned daily. Protectors should be disinfected periodically following the manufacturer's instructions. Observations: Some signs of wear and tear include: yellow colouring of the lenses, superficial scratching of the lenses, scraping etc.

Respiratory

PPE: Filter mask for protection against gases and particles. Characteristics: «CE» marking, category III. The mask must have an anatomically designed form in order to be sealed and watertight. CEN standards: EN 136, EN 140, EN 405, UNE 14387. Maintenance: Should not be stored in places exposed to high temperatures and damp environments before use. Special attention should be paid to the state of the inhalation and exhalation valves in the face adaptor. Observations: Read carefully the manufacturer's instructions regarding the equipment's use and maintenance. Attach the necessary filters to the equipment according to the specific nature of the risk, changing them as advised by the manufacturer. Filter Type needed: A2

Skin/Body

PPE: Anti-static protective and chemical protective clothing. Characteristics: «CE» marking, category II (anti-static protective). Protective clothing should not be too tight or loose in order not to obstruct the user's movements. «CE» marking, category III (chemical protective). Clothing should fit properly. CEN standards: EN 340, EN 1149-(1-2-3-5), EN 13034. Maintenance: In order to guarantee uniform protection, follow the washing and maintenance instructions provided by the manufacturer. Observations: The protective clothing should offer a level of comfort in line with the level of protection provided in terms of the hazard against which it protects, bearing in mind environmental conditions, the user's level of activity and the expected time of use. PPE: Anti-static safety footwear against chemicals. Characteristics: «CE» marking, category III. Check the list of chemicals against which the footwear is resistant. CEN standards: EN ISO 20345. Maintenance: For correct maintenance of this kind of safety footwear, it is necessary to observe the instructions specified by the manufacturer. The footwear should be replaced as soon as any sign of damage is observed. Observations: The footwear should be cleaned regularly and dried when damp, although it should not be placed too close to a source of heat in order to avoid any sharp changes in temperature.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Negro
Colour Intensity
---
Form
---
Odor
Aromatic
Odor Threshold
Not available
Ph
Not available (Substance/mixture is non-soluble (in water))
Melting Point
Not applicable (Not relevant for this type of product)
Boiling Point
100-400 ºC (Standard Test Method for Distillation of Industrial Aromatic Hydrocarbons and Related Materials (ASTM D850)
Flash Point
>23 ºC and < 60ºC (ASTM D 93)
Freezing Point
Not available
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
Not available
Vapor Density
---
Relative Density
> 1,050 gr/ml
Bulk Density
---
Density
---
Flammability
Yes
Upper Explosive Limit
Not available
Lower Explosive Limit
Not available
Explosive Limits
---
Auto Ignition Temperature
(Xylene): 488 ºC
Decomposition Temperature
Not available
Solubility
Not available
Partition Coefficient
Not available
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
10 - 55 Poises
Kinematic Viscosity
165 mm2/s
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under the recommended handling and storage conditions (see section 7).

Reactivity

If the storage conditions are satisfied, does not produce dangerous reactions.

Hazardous reactions

Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised.

Avoid

High temperature, Static discharge, Contact with incompatible materials, Avoid temperatures near or above the flash point, Do not heat closed containers, Avoid direct sunlight and heat, as these may cause a risk of fire.

Incompatible

Strong oxidising agents (peroxy-compounds - peroxosulphuric acid and peroxodisulphuric acid). Strong acids (especially sulfuric and nitric acids). Organic nitrates and inorganic nitrites (in combination with strong acids).

Decomposition

Toxic vapour may be generated in case of thermal decomposition or combustion: carbon monoxide (CO), nitrogen oxides (NOx), sulphur dioxide (SO2), hydrocarbons. Under certain fire conditions, traces of other toxic gases cannot be excluded polycyclic aromatic hydrocarbons.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1999
Shipping Name
TARS, LIQUID
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is TAR 4X P / 5X P known by?

TAR 4X P / 5X P is also known as: Tar 4X P, Tar 5X P

What is the hazard signal word for TAR 4X P / 5X P?

The signal word is danger.

What is the physical form of TAR 4X P / 5X P?

TAR 4X P / 5X P is a liquid with negro color. It has aromatic odor.

What is the solubility of TAR 4X P / 5X P?

Not available

What is TAR 4X P / 5X P used for?

Formulation and end use of coatings, paints, waterproofing material and sealants (adhesives).

What are the hazard statements for TAR 4X P / 5X P?

This substance has 9 hazard statements:

  • H226: Flammable liquid and vapour.
  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H340: May cause genetic defects.
  • H350: May cause cancer.
  • H360FD: May damage fertility. May damage the unborn child.
  • H373: May cause damage to organs through prolonged or repeated exposure.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of TAR 4X P / 5X P?

The melting point is Not applicable (Not relevant for this type of product) and the boiling point is 100-400 ºC (Standard Test Method for Distillation of Industrial Aromatic Hydrocarbons and Related Materials (ASTM D850).