Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- 2500 Hard-Hat® Clear
- Product Form
- Aerosol
Regulatory Identifiers
- CAS Number
- N/A
- UFI Code
- 1KH1-H0WY-300J-9DWK
Identified Uses
Consumer use, Industrial use, Professional use
Uses advised against
None identified.
Manufacturers & Suppliers
Martin Mathys NV
manufacturer
Kolenbergstraat 23, B-3545 Zelem, Belgium
+32 (0) 13 460 200
Tor Coatings Limited
manufacturer
Unit 21, White Rose Way, Follingsby Park, Gateshead, Tyne & Wear, NE10 8YX United Kingdom
+44 (0) 191 4106611
Emergency Contacts
National advisory body/Poison Centre
809 2166
8am to 10pm 7 days per week
Supplier
+353 19014670
24 / 7
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS02
GHS07
Hazard Statements
Precautionary Statements
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Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| dimethyl ether EC: 204-065-8 | 115-10-6 | 50 - 75% | Yes |
| n-butyl acetate EC: 204-658-1 | 123-86-4 | 10 - 20% | Yes |
| Ethylacetate EC: 205-500-4 | 141-78-6 | 10 - 20% | Yes |
| 1-methoxy-2-propanol EC: 203-539-1 | 107-98-2 | 10% | Yes |
| 1-isopropyl-2,2-dimethyltrimethylene diisobutyrate EC: 229-934-9 | 6846-50-0 | 3% | Yes |
| 2-methoxy-1-methylethyl acetate EC: 203-603-9 | 108-65-6 | 3% | Yes |
| maleic anhydride EC: 203-571-6 | 108-31-6 | 0.1% | Yes |
Notes
See Section 16 for the full text of the H statements declared above. Occupational exposure limits, if available, are listed in Section 8. Type [1] Substance classified with a health or environmental hazard Type [2] Substance with a workplace exposure limit
First Aid Measures
Emergency procedures for chemical exposure incidents
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Symptoms: respiratory tract irritation, coughing, nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness
Wash skin thoroughly with soap and water or use recognised skin cleanser. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Symptoms: irritation, dryness, cracking
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Symptoms: pain or irritation, watering, redness
Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Symptoms: No specific data.
Immediate Medical Attention
Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately.
Medical Treatment
No specific treatment.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Use an extinguishing agent suitable for the surrounding fire.
None known.
Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed.
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Firefighter Protection
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material. Wash spillages into an effluent treatment plant.
Materials: water, inert dry material, non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
Related Products
Similar products with comparable safety profiles
Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Put on appropriate personal protective equipment (see Section 8). Pressurised container: protect from sunlight and do not expose to temperature exceeding 50°C. Do not pierce or burn, even after use. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous.
Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources.
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.
Store and use away from heat, sparks, open flame or any other ignition source. Eliminate all ignition sources.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. > 8 hours (breakthrough time): polyethylene (PE), polyvinyl alcohol (PVA). The recommendation for the type or types of glove to use when handling this product is based on information from the following source: EN374.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Use eye protection according to EN 166. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Recommended: organic vapour (Type AX) and particulate filter (EN 140).
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods. Recommended: Personnel should wear antistatic clothing made of natural fibres or of high-temperature-resistant synthetic fibres. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
The product is stable.
No specific test data related to reactivity available for this product or its ingredients.
Under normal conditions of storage and use, hazardous reactions will not occur.
Avoid all possible sources of ignition (spark or flame).
No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
The data for this section has not been processed yet.
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
The generation of waste should be avoided or minimised wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Waste Codes
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- UN1950
- Shipping Name
- AEROSOLS, flammable
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. 63, 190, 277, 327, 344, 381, 959
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Regulatory Information
Chemical regulations, safety assessments, and compliance status
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2020/878
Frequently Asked Questions
Common questions about safety, handling, and properties
What is the hazard signal word for 2500 Hard-Hat® Clear?
The signal word is danger.
What is the physical form of 2500 Hard-Hat® Clear?
2500 Hard-Hat® Clear is a liquid. [aerosol.] with colourless. color. It has hydrocarbon. odor.
What is the solubility of 2500 Hard-Hat® Clear?
cold water Not soluble hot water Not soluble
What is 2500 Hard-Hat® Clear used for?
Consumer use, Industrial use, Professional use
What are the hazard statements for 2500 Hard-Hat® Clear?
This substance has 3 hazard statements:
- H222: Extremely flammable aerosol. Pressurised container: may burst if heated.
- H319: Causes serious eye irritation.
- H336: May cause drowsiness or dizziness.
What is the melting point of 2500 Hard-Hat® Clear?
The melting point is Not available. and the boiling point is Not available..