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Safety Data Sheet EN

Pour-Pac MP-55 Part A

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Pour-Pac MP-55 Part A

Regulatory Identifiers

CAS Number
N/A
REACH No.
not applicable (a mixture, see section 3.2)

Identified Uses

Two-component adhesive for attaching sensors to the road surface

Manufacturers & Suppliers

Vaisala Oyj logo

Vaisala Oyj

manufacturer

Vanha Nurmijärventie 21, 01670 Vantaa, Finland

www.vaisala.com

V

Vaisala LTD

distributor

6230 Bishops Court, Solihull Parkway, Birmingham Business Park, B37 7YB, United Kingdom

+44(0) 121 6831269

F

Fabick Inc.

manufacturer

4118 Robertson Road, Madison, WI 53714, USA

608-242-1100

Emergency Contacts

Emergency Contact

999

NHS 111

111

NHS 24

111

NHS Direct

111

NHS Direct

0845 4647

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H332
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Resp. Sens. Cat. 1 H334
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H335
STOT RE Cat. 2 H373
Carc. Cat. 2 H351

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs (olfactory organs) through prolonged or repeated exposure (inhalation).

Precautionary Statements

P260 Do not breathe dust/gas/mist/vapors/spray.
P264 Wash hands and face thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 In case of inadequate ventilation wear respiratory protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local, regional, national and international regulation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
4,4'-methylenediphenyl diisocyanate EC: 202-966-0 101-68-8 50 - 75% Yes
4,4'-Methylenediphenyl diisocyanate, oligomers EC: 500-040-3 25686-28-6 15 - 25% Yes
methylenediphenyl diisocyanate EC: 247-714-0 26447-40-5 1 - 3% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove the exposed person to fresh air into resting position for easy breathing. In case of breathing difficulties, give oxygen or artificial respiration. Immediate medical attention required.

Symptoms: Allergy or asthma symptoms or breathing difficulties if inhaled, respiratory irritation, wheezing, shortness of breath, difficulty breathing.

Skin contact

Immediately remove contaminated clothing. Wash thoroughly with soap and water. Get medical attention promptly if irritation occurs.

Symptoms: Allergic skin reaction, skin irritation.

Eye contact

Rinse immediately with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediate medical attention required.

Symptoms: Eye irritation.

Ingestion

Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water. Do not give anything by mouth to an unconscious person or in case of convulsions. Immediate medical attention required.

Immediate Medical Attention

Immediate medical attention required for inhalation, eye contact, and ingestion.

Medical Treatment

Treat symptomatically. Treatment should be supportive and based on the judgement of the physician in response to the reaction of the patient.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Foam, Dry Powder, Carbon Dioxide, Water Spray.

Unsuitable media

None known.

Specific hazards

Nitrogen gases, fumes/smoke, isocyanate, vapor.

Instructions

Keep containers cool by spraying with water if exposed to fire.

Firefighter Protection

Fire fighters should use a self-contained breathing apparatus and turn-out gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep unnecessary and unprotected personnel away from the spillage. Clear area. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment.

Small spill

Absorb isocyanates with suitable absorbent material (sand, earth or any suitable adsorbent material). Leave to react for at least 30 minutes. Do not absorb onto sawdust or other combustible materials. Shovel into open container. Do not make container pressure tight. Move container to a well-ventilate area (outside). Wash the spillage area with water. Test atmosphere for MDI vapour.

Large spill

If temporary control of isocyanate vapor is required, a blanket of protein foam or other suitable foam (available from most fire departments) may be placed over the spill. Transfer as much liquid as possible via pump or vacuum device into closed but not sealed containers for disposal.

Environmental

Do not discharge into drains, sewers or watercourses.

Cleanup methods

Wash down spill area with decontamination solution. Allow solution to stand for at least 10 minutes. Dike spillage.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Prevent all exposure. Provide suitable exhaust ventilation at the processing machines. Ensure thorough ventilation of stores and work area. Provide eyewash station and safety shower. Avoid aerosol formation. When handling heated product, vapors of the product should be ventilated, and respiratory protection used. Wear respiratory protection when spraying. Danger of bursting when sealed gastight. Protect against moisture. If bulging of drum occurs, transfer to well ventilated area, puncture to relieve pressure, open vent and let stand for 48 hours before resealing. Take off immediately all contaminated clothing and wash it before reuse. Contaminated work clothing should not be allowed out of the workplace. Clean the equipment, workplace and clothing regularly. Do not eat, drink or smoke in areas where this material is handled and stored. Wash hands before breaks and immediately after handling. Protect from moisture and liquid. Moisture can produce carbon dioxide in the containers, causing high pressure inside the closed container.

Storage

Store properly and use within one year of the package date. Keep away from extreme heat and direct sunlight. Keep from freezing. Store at room temperature. Keep away from humidity and water. Store indoor, in a dry, well-ventilated area. Containers should be tightly sealed to prevent contamination with foreign materials and moisture.

Hygiene

Take off immediately all contaminated clothing and wash it before reuse. Contaminated work clothing should not be allowed out of the workplace. Clean the equipment, workplace and clothing regularly. Do not eat, drink or smoke in areas where this material is handled and stored. Wash hands before breaks and immediately after handling.

Fire prevention

Danger of bursting when sealed gastight.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure sufficient general and local ventilation. In addition to efficient general ventilation, well-functioning local exhaust is provided during high-risk work phases. Ensure that spaces designed to be vacuum remain pressurized. Preferably use tools with built-in local removal. Ensure proper maintenance of air conditioners. Replace the ventilation filters often enough for the air to change as planned. Ensure the adequacy of the replacement air and its correct orientation. Return air is not used in isocyanate work. Spraying work, such as coating, varnishing, open flotation, is carried out in the space provided or deliberately outside normal working hours so that other workers are not exposed unnecessarily. Automatic dispensers are recommended instead of taps and weighing whenever possible, and especially when isocyanates are used extensively. Measure and mix in a fume hood or in a well-ventilated, vacuum room.

Hands

Chemical protective gloves in accordance with EN 374 are always required for handling isocyanates. Used gloves are not caught on the outside and are not stored in your pocket. Multilayer plastic laminates can protect against exposure in all isocyanate work. In particular, they must be used in situations where the gloves are wet. Wearing a handy disposable glove on top of the laminate glove makes working easier. Glove materials suitable for 8 hours: thick nitrile rubber (thickness eg 0.9 mm with knitted lining), thick polyvinyl chloride (PVC, thickness eg 1.5 mm with knitted lining), Viton, butyl rubber, multilayer laminate (trademarks Silvershield and Barrier). Glove materials suitable for 4 hours: neoprene natural rubber (thickness of 0,7 mm or more). Gloves suitable for use for 1 hour: nitrile rubber gloves (thickness of 0,1 mm or more), natural rubber gloves (thickness of 0,5 mm or more).

Eyes

Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.

Respiratory

When a respirator is used as a risk management measure, it shall be selected so that the protective capacity is sufficient to reduce the respirable pollutants to less than 0,1 µg NCO / m³. The face of the mask should also protect the eyes. Only a compressed air hose device is well suited as an effective respirator. Protection devices: type 3A and 4A devices according to EN 14594. As these are difficult to install in all work sites, filter protectors with a fan are also used. TM3A2P class or TH3A2P class devices are recommended as a filter protector with a fan. The filter must be marked SL. The filter fills in use and it is not possible to smell the isocyanates, so the filter must be changed every day, unless the change interval can be estimated otherwise. If isocyanates are heated above 150 °C, the filter must be A2B2E2K2P SL.

Skin/Body

Chemical protective clothing must be worn for work where isocyanates mass is splashed on clothing. The protective clothing must be a type 3 or 4 liquid-tight or splash-proof protective suit which, according to its chemical permeability table, protects against isocyanate and solvents. Isocyanates are absorbed into ordinary clothing and the skin is exposed through clothing. Exposure to bare skin must be prevented. Cover as much of the exposed skin as possible to prevent all skin contact. Suitable materials may include, PVDC-coated material, depending upon conditions of use.

Environmental

Do not release into sewer, drainage systems, soil or water environment.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Vapor Density
not available
Upper Explosive Limit
Not relevant.
Freezing Point
-4 °C
Cloud Point
---
Decomposition Temperature
No decomposition if stored and handled as prescribed/indicated.
Molecular Weight
---
Colour Intensity
---
Physical State
Liquid
Solubility In Fat
---
Boiling Point
200 °C (5 mmHg)
Vapor Pressure
0.00001 mmHg (25 °C)
Density
1,20 g/cm3 (25 °C)
Metal Corrosion
---
Properties Status
---
Partition Coefficient
Unspecified
Evaporation Rate
Value can be approximated from Henry's Law Constant or vapor pressure
Appearance
---
State Under Standard Conditions
---
Form
---
Relative Density
not available
Solubility
reacts with water
Dynamic Viscosity
300 mPa.s (25 °C)
Colour
Light Yellow
Flash Point
> 200 °C (open cup)
Ph
not available
Bulk Density
---
Solidification Point
---
Relative Evaporation Rate
---
Softening Point
---
Auto Ignition Temperature
470 °C
Melting Point
-4 °C
Voc Content
---
Solubility In Water
reacts with water
Kinematic Viscosity
---
Odor
Faintly Aromatic
Flammability
not flammable
Crystallisation Point
---
Explosive Limits
---
Lower Explosive Limit
Not relevant.
Odor Threshold
---
Physical State Data
liquid
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable if stored and handled as prescribed/indicated.

Reactivity

Corrosion to metals: No corrosive effect on metal. Oxidizing properties: Not an oxidizer.

Hazardous reactions

Reacts with water, with formation of carbon dioxide. Risk of bursting. Reacts with alcohols. Reacts with acids. Reacts with alkalies. React with amines. Risk of exothermic reaction. Risk of polymerization. Contact with certain rubbers and plastics can cause brittleness of the substance/product with subsequent loss in strength.

Avoid

Avoid moisture.

Incompatible

Acids, amines, alcohols, water, alkalines, strong bases, substances/products that react with isocyanates.

Decomposition

Carbon monoxide, carbon dioxide, nitrogen oxide, hydrogen cyanide, nitrogen oxides, aromatic isocyanates, gases/vapors.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimized whenever possible.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Pour-Pac MP-55 Part A?

The signal word is danger.

What is the physical form of Pour-Pac MP-55 Part A?

Pour-Pac MP-55 Part A is a liquid with light yellow color. It has faintly aromatic odor.

What is the solubility of Pour-Pac MP-55 Part A?

reacts with water

What is Pour-Pac MP-55 Part A used for?

Two-component adhesive for attaching sensors to the road surface

What are the hazard statements for Pour-Pac MP-55 Part A?

This substance has 8 hazard statements:

  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H319: Causes eye irritation.
  • H332: Harmful if inhaled.
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • H335: May cause respiratory irritation.
  • H351: Suspected of causing cancer.
  • H373: May cause damage to organs (olfactory organs) through prolonged or repeated exposure (inhalation).

What is the melting point of Pour-Pac MP-55 Part A?

The melting point is -4 °C and the boiling point is 200 °C (5 mmHg).