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Safety Data Sheet EN

Toluene/Xylene Mixture

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Toluene/Xylene Mixture
Product Code
NOVA-0008
Synonyms
TOLUENE/XYLENE, T/X, C6-C8 Aromatics, TX Mix

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Gasoline blends, industrial feedstock.

Uses advised against

All uses other than the identified.

Manufacturers & Suppliers

N

NOVA Chemicals

manufacturer

P.O. Box 2518, Station M, Calgary, Alberta, Canada T2P 5C6

1-412-490-4063

Emergency Contacts

NOVA Chemicals

1-800-561-6682

24 hours

NOVA Chemicals

1-403-314-8767

24 hours

CHEMTREC

1-800-424-9300

24 hours

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2
Physical Hazards Not Otherwise Classified (PHNOC) - Static-accumulating flammable liquid Cat. 1
Skin Irrit. Cat. 2
Eye Irrit. Cat. 2
Muta. Cat. 1B
Carc. Cat. 1A
Repr. Cat. 2
STOT SE Cat. 3
STOT RE Cat. 1
STOT RE Cat. 2
Asp. Tox. Cat. 1
Aquatic Acute Cat. 2
Aquatic Chronic Cat. 2

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H225 Highly flammable liquid and vapour.
H242 Sparks may ignite liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H340 May cause genetic defects.
H350 May cause cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure. (Blood)
H373 May cause damage to organs through prolonged or repeated exposure. (Central nervous system) (Hearing organs)
H411 Toxic to aquatic life with long lasting effects.
Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment.
May cause flash fire or explosion.

Precautionary Statements

P202 Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Ground and bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Do not breathe vapours. Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/ protective clothing/ eye protection/ face protection. Avoid release to the environment.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed. Store locked up. Keep cool.
IF SWALLOWED: Immediately call a POISON CENTRE. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing and wash it before reuse. Rinse skin with water [or shower]. If skin irritation occurs: Get medical advice. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTRE if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. IF exposed or concerned: Get medical attention. In case of fire: Use dry chemical, foam, carbon dioxide (CO2), water spray or fog to extinguish. Collect spillage.
Dispose of contents and container in accordance with local regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

All concentrations are percent by weight.

Chemical Name CAS Number Concentration Hazardous
Toluene 108-88-3 69 - 85% No
Benzene, ethyl- 100-41-4 9 - 23% No
Benzene, dimethyl- 1330-20-7 5 - 10% No
Benzene 71-43-2 1% No

This product is considered hazardous by the Hazardous Products Regulations.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTRE if you feel unwell.

Skin contact

Take off immediately all contaminated clothing and wash it before reuse. Rinse skin with water [or shower]. If skin irritation occurs: Get medical advice.

Eye contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Ingestion

Immediately call a POISON CENTRE. Do NOT induce vomiting.

Medical Treatment

Ensure thorough eye and skin decontamination. Treat unconsciousness, nausea, low blood pressure, seizures, and cardiac rhythm disturbances in the conventional manner. If evacuation of stomach contents is considered necessary, use the method least likely to cause aspiration, such as gastric lavage after protecting the airway. Observe hospitalized patients for delayed chemical pneumonia, acute kidney failure, altered level of consciousness, and cardiac rhythm disturbances.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, foam, carbon dioxide (CO2), water spray or fog to extinguish. Use water to cool fire-exposed containers and to protect personnel.

Unsuitable media

Do not use straight/direct streams as this may actually spread flames.

Specific hazards

Highly flammable liquid and vapour. Vapours are heavier than air and may travel to a source of ignition and flash back. Closed containers may rupture violently when heated. Material will float and can be re-ignited on surface of water. Vapours may form explosive mixture with air. Keep containers away from source of heat or fire. This product may be a static accumulator which can form an ignitable vapour-air mixture in a storage tank.

Instructions

Keep upwind. Keep unauthorized personnel away. Move containers from fire area if you can do so without risk. Fight fire from maximum distance or use unmanned holders or monitor nozzles. Immediately withdraw in case of fire and container venting or heat discolouration of a container. Avoid inhaling any smoke and combustion materials. Remove and isolate contaminated clothing and shoes. Cool containers with flooding quantities of water until well after the fire is out.

Firefighter Protection

Wear positive pressure self-contained breathing apparatus (SCBA). Structural fire-fighters' protective clothing provides thermal protection but only limited chemical protection.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear appropriate personal protective equipment. Isolate area. Keep unauthorized personnel away. Alert stand-by emergency and fire-fighting personnel. Monitor surrounding area for buildup of flammable concentrations in air. Do not touch or walk through spilled material. Keep upwind. Keep out of low areas. Stop leak if safe to do so.

Small spill

Remove liquid material with non-sparking approved pumps, skimmers or vacuum equipment. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Use non-sparking tools.

Large spill

Consider downwind evacuation for 300 metres (1000 feet). Dike far ahead of larger spills for later disposal. A vapour-suppressing foam may be used to reduce vapours. Remove pooled liquid material with approved, non-sparking pumps, skimmers or vacuum equipment. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.

Environmental

Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply.

Cleanup methods

Remove liquid material with non-sparking approved pumps, skimmers or vacuum equipment. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal.

Materials: earth, sand or other non-combustible material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Ground and bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Do not breathe vapours. Avoid contact with skin and eyes. Keep away from incompatible materials such as oxidizing agents and acids. Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/ protective clothing/ eye protection/ face protection. In case of inadequate ventilation, use respiratory protection. Avoid release to the environment.

Storage

Storage area should be clearly identified, well-illuminated and clear of obstruction. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Keep cool. Only allow access to authorized persons. Store and handle in properly designed pressure vessels and equipment. Store and use away from heat, sparks, open flame, or any other ignition source. Storage tanks should be above ground and diked to hold entire contents.

Hygiene

Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product.

Fire prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground and bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Have appropriate extinguishing capability in storage area (e.g. sprinkler system, portable fire extinguishers) and flammable gas detectors.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Engineering methods to reduce hazardous exposure are preferred controls. Methods include mechanical ventilation (dilution and local exhaust) process or personal enclosure, remote and automated operation, control of process conditions, leak detection and repair systems, and other process modifications. Ensure all exhaust ventilation systems are discharged to outdoors, away from air intakes and ignition sources. Supply sufficient replacement air to make up for air removed by exhaust systems. Administrative (procedure) controls and use of personal protective equipment may also be required.

Hands

Chemical resistant gloves.

Eyes

Safety glasses. Chemical goggles are recommended if splashing is possible or to prevent eye irritation from vapours.

Respiratory

Appropriate NIOSH approved air-purifying respirator that meets the requirements of CSA Standard CAN/CSA-Z94.4, or self-contained breathing apparatus should be used. Supplied air breathing apparatus must be used when oxygen concentrations are low or if airborne concentrations exceed the limits of the air-purifying respirators or IDLH levels.

Skin/Body

Wear appropriate clothing to prevent any possibility of skin contact. Wear work clothes with long sleeves and pants. If splashing or contact with liquid material is possible, consider the need for an impervious overcoat. Fire resistant (i.e., Nomex) or natural fibre clothing (i.e., cotton or wool) is recommended. Synthetic clothing can generate static electricity and is not recommended where a flammable vapour release may occur. Wear chemical-resistant safety footwear with good traction to prevent slipping. Static Dissipative (SD) rated footwear is also recommended.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Relative Density
0.871 - 0.8715 (15 °C (59 °F)) (Water=1)
Partition Coefficient
3.12 - 3.20
Explosive Limits
---
Upper Explosive Limit
7 %(V) (toluene)
Crystallisation Point
---
Vapor Density
3.18 (Air=1) (toluene) (calculated)
Freezing Point
-80 °C (-112 °F)
Melting Point
-80 °C (-112 °F)
Physical State Data
liquid
Odor Threshold
2 - 5 ppm
Metal Corrosion
---
Solubility In Fat
---
Molecular Weight
---
Relative Evaporation Rate
---
State Under Standard Conditions
---
Solidification Point
---
Solubility
---
Softening Point
---
Physical State
liquid
Cloud Point
---
Bulk Density
---
Colour
Colourless
Density
871.0 - 871.5 kg/m3
Form
liquid
Kinematic Viscosity
2 mm2/s (40 °C (104 °F)), estimated
Evaporation Rate
Medium at 20 °C (68 °F) (n-butyl acetate=1)
Ph
not applicable
Lower Explosive Limit
1 %(V) (toluene)
Properties Status
---
Vapor Pressure
4.8 kPa (37.8 °C (100.0 °F))
Auto Ignition Temperature
450 - 500 °C (842 - 932 °F)
Dynamic Viscosity
---
Voc Content
---
Decomposition Temperature
No data available.
Flammability
not applicable
Boiling Point
110 - 140 °C (230 - 284 °F)
Solubility In Water
Insoluble in water
Appearance
---
Flash Point
4 °C (39 °F)
Colour Intensity
---
Odor
Aromatic
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

Contact with incompatible materials. Sources of ignition. Exposure to heat.

Hazardous reactions

No data available.

Avoid

Exposure to open flame or excessive heat can cause fire or explosion. Keep away from heat, sparks and open flame.

Incompatible

Oxidizing agents, acids.

Decomposition

Upon decomposition, this product emits carbon monoxide, carbon dioxide, low molecular weight hydrocarbons.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Dispose of contents and container in accordance with local regulations. Waste generator is advised to carefully consider hazardous properties and control measures needed for other materials that may be found in the waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN 1993
Shipping Name
FLAMMABLE LIQUID, N.O.S. (Toluene, Ethylbenzene, Xylene (mixed isomers))
Transport Class
3
Packing Group
II
IMDG

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Annex II - yes; IBC02

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Toluene/Xylene Mixture known by?

Toluene/Xylene Mixture is also known as: TOLUENE/XYLENE, T/X, C6-C8 Aromatics, TX Mix

What is the hazard signal word for Toluene/Xylene Mixture?

The signal word is danger.

What is the physical form of Toluene/Xylene Mixture?

Toluene/Xylene Mixture is a liquid with colourless color. It has aromatic odor.

What is Toluene/Xylene Mixture used for?

Gasoline blends, industrial feedstock.

What are the hazard statements for Toluene/Xylene Mixture?

This substance has 14 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H242: Sparks may ignite liquid and vapour.
  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H336: May cause drowsiness or dizziness.
  • H340: May cause genetic defects.
  • H350: May cause cancer.
  • H361: Suspected of damaging fertility or the unborn child.
  • H372: Causes damage to organs through prolonged or repeated exposure. (Blood)
  • H373: May cause damage to organs through prolonged or repeated exposure. (Central nervous system) (Hearing organs)
  • H411: Toxic to aquatic life with long lasting effects.
  • Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment.
  • May cause flash fire or explosion.

What is the melting point of Toluene/Xylene Mixture?

The melting point is -80 °C (-112 °F) and the boiling point is 110 - 140 °C (230 - 284 °F).