Wise Chem E-212-F Part B

Move to fresh air immediately. Oxygen or artificial respiration if needed.

Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. Do not apply greases or ointments. Cover wound with sterile dressing.

Symptoms: skin irritation

Rinse thoroughly with plenty of water, also under the eyelids.

Symptoms: eye irritation

Do not induce vomiting without medical advice. Remove from exposure, lie down.

Use water spray to cool unopened containers. Extinguishing media - large fires:. Alcohol-resistant foam. Extinguishing media - small fires:. Carbon dioxide (CO2). Dry chemical. Dry sand. Limestone powder.

None known.

Heating or fire can release toxic gas. In the event of fire and/or explosion do not breathe fumes. Explosive vapor could form. May generate carbon monoxide gas. May generate toxic nitrogen oxide gases. May generate ammonia gas.

Standard procedure for chemical fires. Use water spray to cool unopened containers.

Keep people away from and upwind of spill/leak. Suppress (knock down) gases / vapors / mists with a water spray jet.

Prevent further leakage or spillage if safe to do so.

Absorb spill with inert material (such as dry sand or earth), then place in appropriate chemical waste container. Transfer to containers by suction, preparatory for later disposal.

Use only in area provided with appropriate exhaust ventilation. Avoid breathing vapors or mists. Avoid contact with skin, eyes and clothing. When using, do not eat, drink or smoke. Emergency showers and eye wash stations should be readily accessible. Keep containers closed when empty. Empty containers may contain explosive vapors. Take precautionary measures against static discharges. Remove all equipment, which may be a source of ignition from vicinity while handling. Avoid using it in any spray application without strict conformance to all applicable electrical codes and the OSHA limit for maximum allowable airborne concentrations. Handle in accordance with good industrial hygiene and safety practice.

Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from acids, oxidizers, heat, flames, sparks. Keep away from heat and sources of ignition. Do not store in reactive metal containers. Ensure all equipment is electrically grounded before beginning transfer operations.

When using, do not eat, drink or smoke. Handle in accordance with good industrial hygiene and safety practice.

Take precautionary measures against static discharges. Remove all equipment, which may be a source of ignition from vicinity while handling.

Stable under normal conditions.

Hazardous polymerization does not occur.

Heat, flames and sparks. Container can be pressurized by carbon dioxide due to reaction with humid air and/or water.

Mineral acids (i.e. sulfuric, phosphoric, etc.). Organic acids (i.e. acetic acid, citric acid, etc.). A reaction accompanied by large heat release occurs when the product is mixed with acids. Heat generated may be sufficient to cause vigorous boiling creating a hazard due to splashing or splattering of hot material. Oxidizing agents (i.e. perchlorates, nitrates, etc.). Reactive metals (i.e. sodium, calcium, zinc, etc.). Oxidizing agents. Sodium hypochlorite. Calcium hypochlorite. Nitrates. CAUTION - N-nitrosamines, many of which are known to be potent carcinogens, may be formed when the product comes in contact with nitrous acid, nitrites or atmospheres with high nitrous oxide concentrations. Product slowly corrodes copper, aluminium, zinc and galvanized surfaces. Reacts violently with peroxides. Water. Reaction with water or contaminants or excessive heat may result in sufficient pressure to burst container.

Thermal decomposition can lead to release of irritating gases and vapors. Highly toxic fumes. Ammonia. Burning produces obnoxious and toxic fumes. Carbon dioxide (CO2). Carbon monoxide (CO). Nitrosamine. Aldehydes. Nitric oxide. Nitrous oxide can react with water vapors to form corrosive nitric acid (TLV=2ppm). Flammable hydrocarbon fragments (e.g., acetylene).

223, 274, 955