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Safety Data Sheet EN

Formic acid, OPTIMA LC/MS Grade (99.5%)

CAS 64-18-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Formic acid, OPTIMA LC/MS Grade (99.5%)
Product Code
A117-50; A117-10X1AMP; A117-1AMP; A117-05AMP; A117-2AMP; NC1450425
Synonyms
Methanoic acid; FA (OPTIMA LC/MS)

Regulatory Identifiers

CAS Number
64-18-6 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

Not for food, drug, pesticide or biocidal product use

Manufacturers & Suppliers

F

Fisher Scientific

distributor

One Reagent Lane, Fair Lawn, NJ 07410

(201) 796-7100

Emergency Contacts

CHEMTREC®

800-424-9300

CHEMTREC®

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3
Acute Tox. Cat. 4
Acute Tox. Cat. 3
Skin Corr. Cat. 1A
Eye Dam. Cat. 1
STOT SE Cat. 2

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

Hazard Statements

H226 Flammable liquid and vapor
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H331 Toxic if inhaled
H335 May cause respiratory irritation

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P233 Keep container tightly closed
P235 Keep cool
P240 Ground/bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting/equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P264 Wash face, hands and any exposed skin thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
P304 + P341 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P310 Immediately call a POISON CENTER or doctor/physician
P330 Rinse mouth
P331 Do NOT induce vomiting
P363 Wash contaminated clothing before reuse
P370 + P378 In case of fire: Use CO2, dry chemical, or foam for extinction
P403 + P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents/container to an approved waste disposal plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Formic acid 64-18-6 95% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Move to fresh air. Immediate medical attention is required. If not breathing, give artificial respiration.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required.

Eye contact

In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Ingestion

Do not induce vomiting. Call a physician or Poison Control Center immediately.

Symptoms: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation.

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically. Possible perforation of stomach or esophagus should be investigated.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Cool closed containers exposed to fire with water spray.

Unsuitable media

No information available

Specific hazards

Flammable. Risk of ignition. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Containers may explode when heated.

Instructions

Cool closed containers exposed to fire with water spray.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.

Environmental

Should not be released into the environment.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: inert absorbent material, suitable, closed containers

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment. Do not get in eyes, on skin, or on clothing. Do not breathe vapors or spray mist. Do not ingest.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Store in explosion-proof refrigerator.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. Take precautionary measures against static discharges. Keep away from heat and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location. Use explosion-proof electrical/ventilating/lighting/equipment. Ensure adequate ventilation, especially in confined areas.

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Tightly fitting safety goggles. Face-shield.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Skin/Body

Chemical resistant apron. Boots. Chemical protection suit (EN 14605).

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Colorless
Colour
---
Colour Intensity
---
Form
---
Odor
pungent
Odor Threshold
No information available
Ph
2.1 10 g/L aq.sol
Melting Point
8 °C / 46.4 °F
Boiling Point
101 °C / 213.8 °F @ 760 mmHg
Flash Point
50 °C / 122 °F
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No information available
Vapor Pressure
44 mbar @ 20 °C
Vapor Density
No information available
Relative Density
1.220
Bulk Density
---
Density
---
Flammability
Not applicable
Upper Explosive Limit
45 vol %
Lower Explosive Limit
10 vol %
Explosive Limits
---
Auto Ignition Temperature
520 °C / 968 °F
Decomposition Temperature
No information available
Solubility
miscible
Partition Coefficient
No data available
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
46.02
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
1.47 mPa.s @ 20 °C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Strong reducing agent. Fire and explosion risk in contact with oxidizing agents. Hygroscopic. heat sensitive. Decomposes to water and carbon dioxide.

Reactivity

None known, based on information available

Hazardous reactions

None under normal processing. Hazardous polymerization does not occur.

Avoid

Incompatible products. Excess heat. Keep away from open flames, hot surfaces and sources of ignition. Exposure to moist air or water.

Incompatible

Strong oxidizing agents, Metals, Powdered metals, Strong bases

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO₂), Hydrogen, Thermal decomposition can lead to release of irritating gases and vapors

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1779
Shipping Name
FORMIC ACID
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Formic acid, OPTIMA LC/MS Grade (99.5%) known by?

Formic acid, OPTIMA LC/MS Grade (99.5%) is also known as: Methanoic acid; FA (OPTIMA LC/MS)

What is the hazard signal word for Formic acid, OPTIMA LC/MS Grade (99.5%)?

The signal word is danger.

What is the physical form of Formic acid, OPTIMA LC/MS Grade (99.5%)?

Formic acid, OPTIMA LC/MS Grade (99.5%) is a liquid appearing as colorless . It has pungent odor.

What is the solubility of Formic acid, OPTIMA LC/MS Grade (99.5%)?

miscible

What is Formic acid, OPTIMA LC/MS Grade (99.5%) used for?

Laboratory chemicals.

What are the hazard statements for Formic acid, OPTIMA LC/MS Grade (99.5%)?

This substance has 5 hazard statements:

  • H226: Flammable liquid and vapor
  • H302: Harmful if swallowed
  • H314: Causes severe skin burns and eye damage
  • H331: Toxic if inhaled
  • H335: May cause respiratory irritation

What is the melting point of Formic acid, OPTIMA LC/MS Grade (99.5%)?

The melting point is 8 °C / 46.4 °F and the boiling point is 101 °C / 213.8 °F @ 760 mmHg.