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Safety Data Sheet EN

Formic acid 30 %, pure

CAS 64-18-6
EC 200-579-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Formic acid 30 %, pure
Product Code
23YP
Chemical Name
Formic acid

Regulatory Identifiers

CAS Number
64-18-6 Check regulations →
EC Number
200-579-1 Check regulations →
REACH No.
not relevant (mixture)
UFI Code
R5U3-P0T3-5004-YTG6

Identified Uses

Laboratory chemical Laboratory and analytical use

Uses advised against

Do not use for squirting or spraying. Do not use for products which come into direct contact with the skin. Do not use for private purposes (household). Food, drink and animal feedingstuffs.

Manufacturers & Suppliers

Carl Roth GmbH + Co. KG logo

Carl Roth GmbH + Co. KG

manufacturer

Schoemperlenstr. 3-5 D-76185 Karlsruhe Germany

+49 (0) 721 - 56 06 0

http://www.carlroth.de

R

ROTH AG

importer

Fabrikmattenweg 12 4144 Arlesheim

ROTH AG logo

ROTH AG

importer

Fabrikmattenweg 12, 4144 Arlesheim, Switzerland

+41 61 7121160

http://www.carlroth.ch

Emergency Contacts

Tox Info Suisse

145

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Met. Corr. Cat. 1 H290
Acute Tox. Cat. 4 H302
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H290 May be corrosive to metals
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage

Precautionary Statements

P261 Avoid breathing mist/vapours
P280 Wear protective gloves/eye protection/face protection
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER/doctor

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Formic acid ...% EC: 200-579-1 64-18-6 30 - 35% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.

Symptoms: Dyspnoea

Skin contact

After contact with skin, wash immediately with plenty of water.

Symptoms: Corrosion

Eye contact

In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. Protect uninjured eye.

Symptoms: Risk of serious damage to eyes, Risk of blindness

Ingestion

Rinse mouth immediately and drink plenty of water. Rinse mouth with water (only if the person is conscious). Call a physician immediately.

Symptoms: If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects).

Immediate Medical Attention

Immediate medical treatment required because corrosive injuries that are not treated are hard to cure. Call a physician immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

co-ordinate firefighting measures to the fire surroundings! water spray, alcohol resistant foam, dry extinguishing powder, BC-powder, carbon dioxide (CO₂)

Unsuitable media

water jet

Specific hazards

Combustible.

Instructions

Fight fire with normal precautions from a reasonable distance.

Firefighter Protection

Wear self-contained breathing apparatus. Wear full chemical protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not breathe vapour/spray.

Environmental

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it.

Cleanup methods

Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents). Place in appropriate containers for disposal.

Materials: sand, diatomaceous earth, acid- or universal binding agents

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle and open container with care. Clear contaminated areas thoroughly.

Storage

Keep container tightly closed.

Hygiene

Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.

Fire prevention

Keep away from sources of ignition - No smoking.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/impermeability prior to use. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. The times are approximate values from measurements at 22 ° C and permanent contact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effective layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred to substance mixtures, they may only be considered as a guide. Type of material: CR: chloroprene (chlorobutadiene) rubber, FKM (fluoro rubber), Butyl caoutchouc (butyl rubber). Material thickness: 0,5 mm. Breakthrough times of the glove material: >480 minutes (permeation: level 6)

Eyes

Use safety goggle with side protection. Wear face protection.

Respiratory

Respiratory protection necessary at: Aerosol or mist formation. Type: E (against acidic gases like sulphur dioxide or hydrogen chloride, colour code: Yellow).

Environmental

Keep away from drains, surface and ground water.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colourless - light yellow
Colour Intensity
---
Form
---
Odor
stinging
Odor Threshold
---
Ph
<2 (20 °C)
Melting Point
not determined
Boiling Point
~100 °C
Flash Point
>65 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
not determined
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1,07[g] /cm³ at 20 °C
Flammability
this material is combustible, but will not ignite readily
Upper Explosive Limit
38 vol% (UEL) (anhydrous)
Lower Explosive Limit
12 vol% (LEL)
Explosive Limits
---
Auto Ignition Temperature
>500 °C
Decomposition Temperature
not relevant
Solubility
---
Partition Coefficient
this information is not available
Solubility In Water
miscible in any proportion
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
Corrosive to metals category 1: corrosive to metals
Dynamic Viscosity
---
Kinematic Viscosity
not determined
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

Reactivity

Substance or mixture corrosive to metals. If heated: Vapours may form explosive mixtures with air.

Hazardous reactions

Danger of explosion: Mixtures of sodium hypochlorite, Metal catalyst, Nitro compound, Hydrogen peroxide. Exothermic reaction with: Alkali hydroxide (caustic alkali), Strong alkali, Oxidisers, Nitric acid, Sulphuric acid, concentrated

Avoid

There are no specific conditions known which have to be avoided.

Incompatible

different metals

Decomposition

Hazardous combustion products: see section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3412
Shipping Name
FORMIC ACID
Transport Class
8
Packing Group
II
ADR

Provisions for dangerous goods (ADR) should be complied within the premises.

IMDG

Provisions for dangerous goods (ADR) should be complied within the premises.

IATA

Provisions for dangerous goods (ADR) should be complied within the premises.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Formic acid 30 %, pure?

The signal word is danger.

What is the physical form of Formic acid 30 %, pure?

Formic acid 30 %, pure is a liquid with colourless - light yellow color. It has stinging odor.

What is Formic acid 30 %, pure used for?

Laboratory chemical Laboratory and analytical use

What are the hazard statements for Formic acid 30 %, pure?

This substance has 3 hazard statements:

  • H290: May be corrosive to metals
  • H302: Harmful if swallowed
  • H314: Causes severe skin burns and eye damage

What is the melting point of Formic acid 30 %, pure?

The melting point is not determined and the boiling point is ~100 °C.